full list of Dr. Tonzetich's publications
Amaya, A.L.; Alawasi, H.; Arman, H.D.; Tonzetich, Z.J. Well-Defined Cobalt-Silyl Complexes and Their Role in Catalytic Carbonyl Hydrosilylation. Organometallics 2023, 42, 2902-2909.
DOI:10.1021/acs.organomet.3c00326
Tonzetich, Z.J. H2S and Bioinorganic Metal Complexes. In Hydrogen Sulfide: Chemical Biology Basics, Detection Methods, Therapeutic Applications, and Case Studies. Pluth, M.D. Ed. Wiley, 2022.
ISBN: 978-1-119-79987-0
Narro, A.L.; Arman, H.D.; Tonzetich, Z.J. Insertion Chemistry of Iron(II) Boryl Complexes. Dalton Trans. 2022, 51, 15475-15483.
DOI:10.1039/d2dt02879d
Thompson, C.V.; Narro, A.L.; Arman, H.D.; Tonzetich, Z.J. Synthesis and Reactivity of Iron(II) Acetylide Complexes Relevant to Alkyne Dimerization. Organometallics 2022, 41, 2291–2300.
DOI:10.1021/acs.organomet.2c00265
Narro, A.L.; Arman, H.D.; Tonzetich, Z.J. Mechanistic Studies of Alkyne Hydroboration by a Well-Defined Iron Pincer Complex: Direct Comparison of Metal-Hydride and Metal-Boryl Reactivity. Inorg. Chem. 2022, 61, 10477-10485.
DOI:10.1021/acs.inorgchem.2c01325
Thompson, C.V.; Arman, H.D.; Tonzetich, Z.J. Investigation of Iron Silyl Complexes as Active Species in the Catalytic Hydrosilylation of Aldehydes and Ketones. Organometallics 2022, 41, 430-440.
DOI:10.1021/acs.organomet.1c00682
Caulfield, K.P.; Tonzetich, Z.J. Alkyl Complexes of Iron(IV) Triphenylcorrole. Organometallics 2022, 41, 155-160.
DOI:10.1021/acs.organomet.1c00635
Tonzetich, Z. J. Biomimetic Metal Thiolates. In Comprehensive Coordination Chemistry III Constable E., Parkin, G. Que, L. Eds. Elsevier, 2021.
DOI:10.1016/B978-0-08-102688-5.00071-4
Alawisi, H.; Arman, H. D.; Tonzetich, Z. J. Catalytic Hydrogenation of Alkenes and Alkynes by a Cobalt Pincer Complex: Evidence of Roles for Both Co(I) and Co(II). Organometallics 2021, 40, 10621070.
DOI:10.1021/acs.organomet.1c00053
(The ouroboros, regarded as a symbol of cyclic renewal or rebirth, has long occupied a special place in the alchemical tradition. Here, the image captures the nature of the dual catalytic cycles discussed by Tonzetich and co-workers. The authors find that both cobalt(I) and cobalt(II) can play a role in the hydrogenation of alkenes and alkynes catalyzed by pincer-type complexes. Moreover, the interplay of these two catalytic cycles leads to different product outcomes. Allusions to alchemical themes are further highlighted in the cover image through the use of the alchemical symbols for cobalt and "PNP.")
Saber, M.R.; Przyojski, J.A.; Tonzetich, Z.J.; Dunbar, K.R. Slow magnetic relaxation in cobalt N-heterocyclic carbene complexes. Dalton Trans. 2020, 49, 11577-11582.
DOI:10.1039/D0DT02286A
Thompson, C.V.; Tonzetich, Z.J. Pincer ligands incorporating pyrrolyl units: Versatile platforms for organometallic chemistry and catalysis. Adv. Organomet. Chem. 2020, 74, 153-240.
DOI:10.1016/bs.adomc.2020.04.004
Pluth, M.D.; Tonzetich, Z.J. Hydrosulfide complexes of the transition elements: diverse roles in bioinorganic, cluster, coordination, and organometallic chemistry. Chem. Soc. Rev. 2020, 49, 4070-4134.
DOI:10.1039/C9CS00570F
Hartley, R.; Tonzetich, Z.; Wrigth, N.; Henry, C. Investigation into Low-Temperature Urea-Water Solution Decomposition by Addition of Titainium-Based Isocyanic Acid Hydrolysis Catalyst and Surfactant. SAE Int. J. Adv. & Curr. Prac. in Mobility 2(4):2356-2373, 2020.
DOI:10.4271/2020-01-1316
Madera, J.; Slattery, M.; Arman, H.D.; Tonzetich, Z.J. Suzuki-Miyaura Coupling Catalyzed by a Ni(II) PNP Pincer Complex: Scope and Mechanistic Insights. Inorg. Chim. Acta 2020, Volume 504, 1 May 2020, 119457. (Special issue honoring the career of Professor Tara P. Dasgupta)
DOI:10.1016/j.ica.2020.119457
Krzystek, J.; Schnegg, A.; Aliabadi, A.; Holldack, K.; Stoian, S. A.; Ozarowski, A.; Hicks, S.D.; Abu-Omar, M.M.; Thomas, K.E.; Ghosh, A.; Caulfield, K.P.; Tonzetich, Z.J.; Telser, J. Advanced Paramagnetic Resonance Studies on Manganese and Iron Corroles with a Formal d4 Electron Count. Inorg. Chem. 2020, 59, 1075-1090.
DOI:10.1021/acs.inorgchem.9b02635
Caulfield, K.P.; Conradie, J.; Arman, H.D.; Ghosh, A.; Tonzetich, Z.J. Iron(II) Corrole Anions. Inorg. Chem. 2019, 58, 15225-15235.
DOI:10.1021/acs.inorgchem.9b02209
Thompson, C.V.; Arman, H.D.; Tonzetich, Z.J. Square-Planar Iron(II) Silyl Complexes: Synthesis, Characterization, and Insertion Reactivity. Organometallics 2019, 38, 2979-2989.
DOI:10.1021/acs.organomet.9b00335
Hartley, R.; Henry, C.; Eakle, S.; Tonzetich, Z. Deposit Reduction in SCR Aftertreatment Systems by Addition of Ti-Based Coordination Complex to UWS. SAE Technical Paper 2019, 2019-01-0313.
DOI:10.4271/2019-01-0313
Yue, Y.; Arman, H.D.; Tonzetich, Z.J.; Chen, B. Air-Free Synthesis of a Ferrous Metal-Organic Framework Featuring HKUST-1 Structure and its Mössbauer Spectrum. Z. Anorg. Allg. Chem. 2019, 645, 797-800.
DOI:10.1002/zaac.201900066
Narro, A.L.; Arman, H.D.; Tonzetich, Z.J. Manganese Chemistry of Anionic Pyrrole-Based Pincer Ligands. Organometallics. 2019, 38, 1741-1749.
DOI:10.1021/acs.organomet.9b00058
Alawisi, H.; Al-Afyouni, K.F.; Arman, H.D.; Tonzetich, Z.J. Aldehyde Decarbonylation by a Cobalt(I) Pincer Complex. Organometallics. 2018, 37, 4128-4135.
DOI:10.1021/acs.organomet.8b00668
Krishnan, V.M.; Davis, I.; Baker, T.M.; Curran, D.J.; Arman, H.D.; Neidig, M.L.; Liu, A.; Tonzetich, Z.J. Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands. Inorg. Chem. 2018, 57, 9544-9553.
DOI:10.1021/acs.inorgchem.8b01643
Krishnan, V.M.; Arman, H.D.; Tonzetich, Z.J. Preparation and Reactivity of a Square-Planar PNP Cobalt(II)–Hydrido Complex: Isolation of the First {Co–NO}8–Hydride. Dalton Trans. 2018, 47,1435–1441. (Inside Front Cover)
DOI:10.1039/C7DT04339B
Thompson, C.V.; Davis, I.; DeGayner, J.A.; Arman, H.D.; Tonzetich, Z.J. Iron Pincer Complexes Incorporating Bipyridine: A Strategy for Stabilization of Reactive Species. Organometallics 2017, 36, 4928–4935.
DOI:10.1021/acs.organomet.7b00772
Thompson, C.V.; Arman, H.D.; Tonzetich, Z.J. A Pyrrole-Based Pincer Ligand Permits Access to Three Oxidation States of Iron in Organometallic Complexes. Organometallics 2017, 36, 1795-1802.
DOI:10.1021/acs.organomet.7b00144
Krishnan, V.M.; Arman, H.D.; Tonzetich, Z.J. Synthesis and Characterisation of Ruthenium-Nitrosyl Complexes in Oxygen-Rich Ligand Environments. Dalton Trans. 2017, 46, 1186-1193.
DOI:10.1039/C6DT04717C
Meininger, D.J.; Arman, H.D.; Tonzetich, Z.J. Synthesis, Characterization, and Binding Affinity of Hydrosulfide Complexes of Synthetic Iron(II) Porphyrinates. J. Inorg. Biochem. 2017, 167, 142-149.
DOI:10.1016/j.jinorgbio.2016.08.014
Meininger, D.J.; Chee-Garza, M.; Arman, H.D.; Tonzetich, Z.J. Gallium(III) Tetraphenylporphyrinates Containing Hydrosulfide and Thiolate Ligands: Structural Models for Sulfur-Bound Iron(III) Hemes. Inorg. Chem. 2016, 55, 2421-2426.
DOI:10.1021/acs.inorgchem.5b02822
Meininger, D.J.; Kasrawi, Z.; Arman, H.D.; Tonzetich, Z.J. Synthesis of Tetraphenylporphyrinate Manganese(III) Siloxides by Silyl Group Transfer from Silanethiols. J. Coord. Chem. 2016, 69, 1970. (Special issue on emerging investigators in coordination chemistry)
DOI:10.1080/00958972.2016.1187727
Bartley, G.; Tonzetich, Z.; Hartley, R. Ruthenium-Based Catalyst in EGR Leg of a D-EGR Engine Offers Combustion Improvements through Selective NOx Removal. SAE Technical Paper 2016, 2016-01-0952.
DOI:10.4271/2016-01-0952
Hartle, M.D.; Meininger, D.J.; Zakharov, L.N.; Tonzetich, Z.J.; Pluth, M.D. NBu4SH Provides a Convenient Source of HS– Soluble in Organic Solution for H2S and Anion-Binding Research. Dalton Trans. 2015, 44, 19782.
DOI:10.1039/C5DT03355A
Przyojski, J.A.; Veggeberg, K.P.; Arman, H.D.; Tonzetich, Z.J. Mechanistic Studies of Catalytic Carbon−Carbon Cross-Coupling by Well-Defined Iron NHC Complexes. ACS Catal. 2015, 5, 5938-5946.
DOI:10.1021/acscatal.5b01445
Przyojski, J.A.; Kiewit, M.L.; Fillman, K.L.; Arman, H.D.; Tonzetich, Z.J. Homoleptic Transition Metal Complexes of the 7‐Azaindolide Ligand Featuring κ1‐N1 Coordination. Inorg. Chem. 2015, 54, 9637-9645.
DOI:10.1021/acs.inorgchem.5b01732
Al-Afyouni, M.H.; Krishnan, V.M.; Arman, H.D.; Tonzetich, Z.J. Synthesis and Reactivity of Manganese(II) Complexes Containing N‐Heterocyclic Carbene Ligands. Organometallics 2015, 34, 5088−5094.
DOI:10.1021/acs.organomet.5b00684
Meininger, D.J.; Muzquiz, N.; Arman, H.D.; Tonzetich, Z.J. Synthesis, Characterization, and Atropisomerism of Iron Complexes Containing the Tetrakis(2-chloro-6-fluorophenyl)porphyrinate Ligand. Dalton Trans. 2015, 44, 9486-9495.
DOI:10.1039/C5DT01122A
Fillman, K.L.; Przyojski, J.A.; Al-Afyouni, M.H.; Tonzetich, Z.J.; Neidig, M.L. A Combined Magnetic Circular Dichroism and Density Functional Theory Approach for the Elucidation of Electronic Structure and Bonding in Three- and Four-Coordinate Iron(II)-N-Heterocyclic Carbene Complexes. Chem. Sci. 2015, 6, 1178-1188.
DOI:10.1039/C4SC02791D
Shupp, J.P.; Kinne, A.S.; Arman, H.D.; Tonzetich, Z.J. Synthesis and Characterization of Molybdenum(0) and Tungsten(0) Complexes of Tetramethylthiourea: Single-Source Precursorsfor MoS2 and WS2. Organometallics 2014, 33, 5238–5245.
DOI:10.1021/om500567y
Venkanna, G.T.; Arman, H.D.; Tonzetich, Z.J. Catalytic C-S Cross-Coupling Reactions Employing Ni Complexes of Pyrrole-Based Pincer Ligands. ACS Catal. 2014, 4, 2941-2950.
DOI:10.1021/cs500874z
Meininger, D.J.; Muzquiz, N.; Arman, H D.; Tonzetich, Z.J. A Convenient Procedure for the Synthesis of Fluoro-Iron(III) Complexes of Common Synthetic Porphyrinates. J. PorphyrinsPhthalocyanines 2014, 18, 416–423.
DOI:10.1142/S108842461450014X
Meininger, D.J.; Caranto, J.D.; Arman, H.D.; Tonzetich, Z.J. Studies of Iron(III) Porphyrinates Containing Silanethiolate Ligands. Inorg. Chem. 2013, 52, 12468–12476.
DOI:10.1021/ic401467k
Tonzetich, Z.J. Nucleophilic Carbenes of the Chromium Triad. in Contemporary Carbene Chemistry Doyle, M. and Moss, R. Eds. Wiley, 2013.
DOI:10.1002/9781118730379.ch14
Venkanna, G.T.; Tammineni, S.; Arman, H.D.; Tonzetich, Z.J. Synthesis, Characterization, and Catalytic Activity of Ni(II) Alkyl Complexes Supported by Pyrrole- Diphosphine Ligands. Organometallics 2013, 32, 4656–4663.
DOI:10.1021/om400630q
Przyojski, J.A.; Arman, H.D.; Tonzetich, Z.J. NHC Complexes of Co(II) Relevant to Catalytic C-C Coupling Reactions. Organometallics 2013, 32, 723–732.
DOI:10.1021/om3010756
Venkanna, G.T.; Ramos, T.V.M.; Arman, H.D.; Tonzetich, Z.J. Nickel(II) Complexes Containing a Pyrrole–Diphosphine Pincer Ligand. Inorg. Chem. 2012, 51, 12789–12795.
DOI:10.1021/ic301633q
Przyojski, J.A.; Arman, H.D.; Tonzetich, Z.J. Complexes of Iron(II) and Iron(III) Containing Aryl-Substituted N-Heterocyclic Carbene Ligands. Organometallics 2012, 31, 3264–3271.
DOI:10.1021/om300106u
